Advice on PS2/Rockband and Wii/Gamecube

Hi, wondering if someone can give me some advice on firstly PS2, Kids have the guitar hero band in a box on PS2, someone told me that it will play the Rockband games with the guitar hero instruments, don`t want to waste my dosh if this is not the case, can someone clarify this to be the case for me.
Now we also have the Wii, kids want to play some of the old Pokemon Gamecube games, i have got a cpl of the classic wii controllers, is that all i need or will i need to get some sort of memory card to play gamecube games on the wii, thanks for any replys

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