Itunes help - NAS server

I did have itunes on my macbook, i bought a western digital NAS external hard drive (a deal posted on HDUK) which is 2tb.
I transferred all my itunes over to the external hard drive and in itunes, advanced options, made this the default place to find my itunes.

The problem i'm having is, when i restart my computer, my laptop is the default itunes, i keep changing it to the external hard drive but it just won't remain as that.... also when i back up my iphone, it says my pictures folder can't be located.

Is there anyone with a better knowledge of Itunes that can help me out?
Rep for those that can!

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